Polyphosphonate-based Safe Electrolytes for Zinc-ion Batteries
il y a 5 jours
**POLYPHOSPHONATE-BASED SAFE ELECTROLYTES FOR ZINC-ION BATTERIES (POLYSAFE-ZIB)**:
- Réf **ABG-131478**
- Sujet de Thèse
- 27/04/2025
- Contrat doctoral
- CARMeN Institut
- Lieu de travail- CAEN - Normandie - France
- Intitulé du sujet- POLYPHOSPHONATE-BASED SAFE ELECTROLYTES FOR ZINC-ION BATTERIES (POLYSAFE-ZIB)
- Champs scientifiques- Chimie
- Matériaux
- Mots clés- solid electrolyte, phosphonates, ROMP polymerisation
**Description du sujet**:
- Due to the large production of polymers, the chemical recycling of polymer wastes, which would offer a sustainable polymer reusing technology, is of major importance. Polyurethanes (PUs) are a wide family of polymers which are used in a broad range of sectors, from adhesive coatings, to automotive and construction industries. Unfortunately, the current practices in the generation and disposal of PU polymers are largely unsustainable.
- The aim of this project is to develop PU in a sustainable way, through the involvement of a Diels-Alder/retro-Diels-Alder cycle and by combining two approaches:
- The first one consists in synthesizing PU networks from elastomer wastes such as tires wastes. Functionalizations of tires wastes through metathesis reactions is envisaged in this context;
- The second aims at designing reversible cross-linked PU networks using the thermally reversible DA reaction, with a particular interest in studying the impact of the nature of the adducts and the influence of the crosslink density on the thermomechanical properties of the networks and their recyclability.
**Prise de fonction**:
- 01/10/2025
**Nature du financement**:
- Contrat doctoral
**Précisions sur le financement**:
- University of Caen funding 3 years position
**Présentation établissement et labo d'accueil**:
- CARMeN Institut
This research project will be carried out in the polymer group of LCMT. The « Laboratoire de chimie Moléculaire et Thioorganique » (LCMT, Caen) is a part of the « Institut Normand de Chimie Moléculaire, Médicinale et Macromoléculaire » (INC3M Federation). With more than 200 researchers, INC3M meets the requirements for a high quality level of research in the fields of organic synthesis, macromolecules, and medicinal chemistry. LCMT is also a part of two laboratories of excellence **:Labex Synorg** et **Labex EMC**3** and of the Carnot Institute **Innovation Chimie Carnot (I2C)**. LCMT is a major player in the field of the molecular and macromolecular chemistry. It participates in national (ANR) and European projects (INTERREG IV, COST). In addition, it has developed various long-term public-private partnerships with chemical industries and research institutions in France and abroad.
**Site web**:
**Intitulé du doctorat**:
- Doctorat de Chimie
**Pays d'obtention du doctorat**:
- France
**Etablissement délivrant le doctorat**:
- Normandie Université
**Ecole doctorale**:
- École Doctorale normande de chimie (EDNC)- 30/05/2025
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