Reactor Study for Catalytic Dehydrogenation of
il y a 4 semaines
Réf **ABG-123866**
- Sujet de Thèse- 14/05/2024- Autre financement public- Laboratoire d'Automatique, de Génie des Procédés et de Génie Pharmaceutique (CNRS UCBL UMR5007)- Lieu de travail- Villeurbanne (Lyon) - Auvergne-Rhône-Alpes - France- Intitulé du sujet-
- Champs scientifiques- Génie des procédés
- Mots clés- Chemical engineering, LOHC, Hydrogen storage, catalytic reactor, hydrodynamics**Description du sujet**:
**Context**:
Today, hydrogen appears to be a key energy vector for sustainable and future process development in the world: it is expected to be a means of storing and transporting renewable energy.
However, its transport and storage remain problematic due to its explosiveness and its low molecular density. A possible alternative to gaseous storage under pressure, liquid or in the form of metal hydrides is chemical storage in the form of hydrogenated organic compounds (LOHC: Liquid Organic Liquid Carrier). Thanks to the high mass and volume density of hydrogenated compounds (5 - 8 wt%, 50-70 gH2/L) and their stability under ambient conditions, it is possible to transport and store them at atmospheric pressure and room temperature in existing oil tanks and means of transportation without leakage of molecules or heat loss, as well as to be an economical solution. The process idea is to store H2 by catalytic reversible exothermic hydrogenation (HYD) of H2-lean (H0-LOHC) molecules at moderate temperature and high pressure (30 bar, 180°C, ΔrH°= - 50,5 kJ/molH2) while endothermic dehydrogenation (DH) on H2-rich (Hx-LOHC) molecules takes place at moderate pressure and higher temperature ((2-3 bar, 200°C, ΔrH°=50,5 kJ/molH2).
The objectives of the French ANR RID-LOHC project are to study and design reactors suitable for hydrogenation and dehydrogenation reactions on mixtures of N-ethyl and N-propyl-carbazole (NEC+NPC). The project tasks include the steps necessary to achieve these objectives, which are kinetic studies of the reactions, measurements of thermodynamic properties, design, optimisation and construction of reactors. To carry out this study, three academic laboratories and an industrial partner are collaborating.
**PhD problematic**:
The PhD student will work on the study of the dehydrogenation reaction of perhydro-N-alkylcarbazoles and the study and design of reactors adapted to the constraints of the reaction as part of the ANR RID LOHC project. The thesis will follow the following scientific programme
- Carry out a complete bibliographical study of the selected molecules.
- Carry out experimental tests to study the dehydrogenation kinetics of a mixture of perhydro-N-alkylcarbazoles in a fixed bed reactor in order to collect experimental data under different conditions of temperature, pressure and flow rate. Establish the kinetic model for the dehydrogenation of the mixture of interest and estimate the kinetic parameters of interest.
- Participate in the design of the dehydrogenation reactor with the industrial partner based on the experimental data.
- Experimentally measure the hydrodynamic and catalytic performances of the designed reactors and model their dynamic behaviour in order to assess any limitations on heat/material transfer, but also the hydrodynamic behaviour of the phases.
**Prise de fonction**:
- 01/10/2024**Nature du financement**:
- Autre financement public**Précisions sur le financement**:
- Contrat sur projet ANR financé**Présentation établissement et labo d'accueil**:
- Laboratoire d'Automatique, de Génie des Procédés et de Génie Pharmaceutique (CNRS UCBL UMR5007)The Laboratory of Automatic Control, Chemical and Pharmaceutical Engineering (University Claude Bernard de Lyon/CNRS) is a multidisciplinary laboratory that covers the fields of process engineering, automation, engineering products, pharmaceutical engineering and physicochemistry. The objective of the laboratory is to conduct cross-cutting research projects involving researchers from different disciplinary fields while ensuring the maintenance of high-level scientific work and experimentation in each disciplinary field. The research activities of this PhD project will be conducted by chemical engineers from two research teams, located at Villeurbanne (Lyon): DYCOP (Dynamics, Control and Observation of Processes) and PRODIS (Processes in Dispersed Media). The chemical engineers involved in the project are specialised in the implementation of dynamic phenomena and the study and modelling of dynamic behaviour of heat transfer and phase change. They are well-known in the topic of LOHC and catalytic reactors.
**Site web**:
**Intitulé du doctorat**:
- Doctorat de Chimie de Lyon, option Procédés**Pays d'obtention du doctorat**:
- France**Etablissement délivrant le doctorat**:
- UNIVERSITE CLAUDE-BERNARD-LYON 1**Ecole doctorale**:
- École Doctorale de chimie (chimie, procédés, environnement)Master or Engineer in chemical engineering. Interest in reactor experimentation and m
-
Global Study Manager
il y a 1 mois
Lyon, France Excelya Temps pleinCreated in 2014, Excelya is a people-centered Contract Research Organization (CRO) that excels with care. We offer a personal and authentic experience within a young, ambitious health company on the path to becoming the clinical research leader in Europe thanks to our 800 Excelyates. Our unique one-stop provider service model - leveraging full-service,...
-
Study Start Up Associate Ii
il y a 1 mois
Lyon, France ICON plc Temps pleinStudy Start Up Associate II At ICON, it’s our people that set us apart. Our diverse teams enable us to become a better partner to our customers and help us to fulfil our mission to advance and improve patients’ lives. Our ‘Own It’ culture is driven by four key values that bring us together as individuals and set us apart as an organisation:...
-
Operational Controlling Analyst
Il y a 2 mois
Lyon, France Mantu Temps plein**Who are we?**: **Mantu** is an international company providing guidance and services to businesses and entrepreneurs. We ourselves are entrepreneurs: we started out from scratch and built a successful business based on our values and our “Tomorrow is human” vision. We constantly generate opportunities for a vast talent community and encourage our team...
-
Administrative Study Coordinator F/m
il y a 1 semaine
Lyon, France bioMérieux Temps pleinA family-owned company, bioMérieux has grown to become **a world leader in the field of in vitro diagnostics**. For 60 years and across the world, we have imagined and developed **innovative diagnostics solutions** to **improve public health**. Today, our teams are spread across 45 countries and serve 160 countries with the support of a large distribution...
-
Coordinator Logistic Study F/m
il y a 7 jours
Lyon, France bioMérieux Temps pleinA family-owned company, bioMérieux has grown to become **a world leader in the field of in vitro diagnostics**. For 60 years and across the world, we have imagined and developed **innovative diagnostics solutions** to **improve public health**. Today, our teams are spread across 45 countries and serve 160 countries with the support of a large distribution...
-
Population Balance Method in Organic Liquids for
il y a 1 mois
Lyon, France IFP Energies nouvelles Temps plein**Population balance method in organic liquids for bubble column reactors**: - Réf **ABG-120138** - Sujet de Thèse- 08/02/2024- Contrat doctoral- IFP Energies nouvelles- Lieu de travail- Lyon - Auvergne-Rhône-Alpes - France- Intitulé du sujet- Population balance method in organic liquids for bubble column reactors- Champs scientifiques- Chimie - Mots...
-
Design Office Study Coordinator
il y a 5 jours
Lyon, France Solvay Temps pleinSolvay is a science company whose technologies bring benefits to many aspects of daily life. Our purpose—we bond people, ideas and elements to reinvent progress—is a call to go beyond, to reinvent future forms of progress and create sustainable shared value for all through the power of science. In a world facing an ever-growing population and quest for...
-
Global Medical Affairs Study Coordinator F/m
il y a 1 mois
Lyon, France bioMérieux Temps pleinA family-owned company, bioMérieux has grown to become **a world leader in the field of in vitro diagnostics**. For 60 years and across the world, we have imagined and developed **innovative diagnostics solutions** to **improve public health**. Today, our teams are spread across 45 countries and serve 160 countries with the support of a large distribution...
-
Thermochemical Heat Storage
Il y a 2 mois
Lyon, France Ecole des Mines de Saint-Etienne Temps pleinduring the following cycles. In order to predict the behaviour of the materials among the storage cycles, it is crucial to determine reliable kinetic models of both reactions and to quantify the modelling uncertainties. The goals of this PhD thesis will be 1) to study the gas-solid reaction experimentally, 2) to model it and then 3) to quantify the...
-
Work-study Marketing
il y a 1 mois
Lyon, France Nexans Temps plein**Lieu**:Lyon, 69, FR, 69007**Fonction**:Technique**Type d'emploi**:Temps plein**Expérience requise**:Etudiant**N° de l'offre**:74757Work-study Marketing & Communication Assistant **VOUS INTÉGRER DANS L'ENTREPRISE** - Chez Nexans, notre vision globale est d'électrifier le futur. Au sein du Groupe, cela signifie innover au-delà du câble pour apporter...
-
Work-study Marketing
il y a 1 mois
Lyon, France Nexans Temps plein**Location**:Lyon, 69, FR, 69007**Function**:Technical**Employment type**:Full Time**Required experience**:Student**Reference ID**:74757Work-study Marketing & Communication Assistant **ONBOARDING YOU TO THE COMPANY** - At Nexans our global vision is to electrify the future. At Nexans' Innovation Business Group this means innovation beyond cable to bring...
-
Process Validation for Biological Safety
Il y a 2 mois
Lyon, France Talents Solutions Temps pleinThe Company: The company is an innovative French company of 30 people specializing in the design and manufacture of orthopedic Medical Devices for extremity surgery. The expectations regarding practitioners' performance are constantly increasing, regulatory requirements are rising, and the optimization of technical platforms is a necessity. In this...
-
Process Validation for Biological Safety
il y a 1 semaine
Lyon, France Talents Solutions Temps pleinThe Company: The company is an innovative French company of 30 people specializing in the design and manufacture of orthopedic Medical Devices for extremity surgery. The expectations regarding practitioners' performance are constantly increasing, regulatory requirements are rising, and the optimization of technical platforms is a necessity. In this...
-
Biostatistician Lyon
Il y a 2 mois
Lyon, France Resourcing Life Science Temps pleinJob Overview - Date Posted - 12/06/2023 - Location - Lyon, France **Company Description** Our client is a Global CRO currently supporting various Pharmaceutical & Biotech companies globally. They offer a full service solution encompassing clinical & non-clinical development, peri-approval & market access. They are currently seeking a Biostatistician office...
-
Biostatistician Lyon
il y a 3 jours
Lyon, France Resourcing Life Science Temps plein**Company Description** Our client is a Global CRO currently supporting various Pharmaceutical & Biotech companies globally. They offer a full service solution encompassing clinical & non-clinical development, peri-approval & market access. They are currently seeking a Biostatistician office based in Lyon. **Job Overview** - Contribute to clinical...
-
Physically-driven Design of Health Indicators for
Il y a 2 mois
Lyon, France Laboratoire Vibrations Acoustique Temps plein**Physically-driven design of health indicators for diagnosis and prognosis**: - Réf - **ABG-119848** - Sujet de Thèse- 31/01/2024- Financement de l'Union européenne- Laboratoire Vibrations Acoustique- Lieu de travail- Lyon - Auvergne-Rhône-Alpes - France- Intitulé du sujet- Physically-driven design of health indicators for diagnosis and prognosis-...
-
Using Artificial Intelligence for The Development
il y a 1 mois
Lyon, France Laboratoire de Biométrie et Biologie Evolutive (LBBE), Lyon Temps plein**Using Artificial Intelligence for the Development of a Clinical Prediction Model in Clinical Toxicology (TOX-KBS)**: - Réf - **ABG-110251** - Stage master 2 / Ingénieur- Durée 6 mois- Salaire net mensuel 500- 15/01/2023- Laboratoire de Biométrie et Biologie Evolutive (LBBE), Lyon- Lieu de travail- lyon Auvergne-Rhône-Alpes France- Champs...
-
Clinical Research Associate
Il y a 2 mois
Lyon, France EastHORN Clinical Services Temps plein**Job summary**: As a **Clinical Research Associate **you will be expected to actively participate in and manage the recruitment of potential investigators and perform CA and EC submissions. You will be responsible for monitoring of clinical sites, maintenance of study files, conduct of pre-study and initiation visits, liaison with vendors and other duties....
-
Chargé D’études Techniques
il y a 1 semaine
Lyon, France newcleo Temps pleinLocation **Lyon (France)** Department **Projets** Status **Full-Time** Years of experience **N.D.** *** **_new_**cleo is a clean and safe nuclear technology company. Privately funded and headquartered in London, UK, **_new_**cleo was launched in 2021 to be a disruptor in the field of nuclear energy. Its mission is to generate safe, clean, economic...
-
Chargé D’études Techniques
il y a 1 semaine
Lyon, France newcleo Temps pleinLocation **Lyon (France)** Department **Projets** Status **Full-Time** Years of experience **N.D.** *** **_new_**cleo is a clean and safe nuclear technology company. Privately funded and headquartered in London, UK, **_new_**cleo was launched in 2021 to be a disruptor in the field of nuclear energy. Its mission is to generate safe, clean, economic...
